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51.
Herein, we successfully construct the 3D biocompatible graphene through crosslinking 2D graphene nanosheet onto carbon fiber paper with poly(diallyldimethylammonium chloride) (PDDA) as anode of the alcohol biofuel cell. Compared with the bioanode without 3D graphene, the current density and output power of PDDA-graphene-ADH bioanode is increased by 23 % and 41 % at a high concentration of ethanol at pH 8.9, suggesting the stabilization role of graphene in enzyme loading. The study provides us a deep analysis on structures and performances of the bioanode incl. electrochemistry, X-ray photoelectron spectra, and atomic force microscopy images, which is significant to develop the new methods to construct 3D porous electrodes in energy conversion device. 相似文献
52.
53.
中空介孔SiO2由于中空多孔的结构而常用作功能材料的基底.将中空介孔SiO2进行官能团修饰,并应用为荧光传感材料是中空介孔SiO2一个重要的研究领域.本论文采用聚丙烯酸(PAA)为中空模板,聚醚F127为造孔剂,正硅酸乙酯(TEOS)为硅源,氨水为催化剂在乙醇体系中制备了中空介孔SiO2纳米球.系统研究了搅拌速度和聚醚F127引入量对中空介孔SiO2纳米球形貌及比表面积的影响.通过透射电镜、N2-等温吸附脱附曲线等表征说明该合成方法具有很好的普适性,通过调节F127的引入可以实现对比表面积的有效控制.通过氨基化、席夫碱反应进行荧光修饰,进一步研究表明荧光修饰后的中空介孔SiO2纳米球在水溶液中能够实现对Al3+的有效检测,检测限为1.19×10 -7M. 相似文献
54.
Enyuan Wang Xiangguo Kong Shaobin Hu Zhonghui Li Quanlin Liu 《Transport in Porous Media》2018,121(3):703-724
With coal mining entering the geological environment of “high stress, rich gas, strong adsorption and low permeability,” the difficulty of joint coal and gas extraction clearly augments, the risk of solid–gas coupling dynamic disasters greatly increases, and the underlying mechanisms become more complex. In this paper, based on the characteristics of coal’s multi-scale structure and spatiotemporal variation, the multi-scale fractured coal gas–solid coupling model (MSFM) was built. In this model, the interaction between coal matrix and its fractures and the mechanical characteristics of gas-bearing coal were considered, as well as their coupling relationship. By MATLAB software, the stress–damage–seepage numerical computation programs were developed, which were applied into Comsol Multiphysics to simulate gas flow caused by coal mining. The simulation results showed the spatial variability of coal elastic modulus and cross-flow behaviors of coal seam gas, which were superior to the results of traditional gas–solid coupling model. And the numerical results obtained from MSFM were closer to the measured results in field, while the computation results of traditional model were slightly higher than the measured results. Furthermore, the MSFM in a large scale was verified by field engineering project. 相似文献
55.
Chen Yujie Sang Weixuan Chen Rong Liu Xue Li Xiaoyan Guan Fenfen Li Xun Xiao Hui 《Journal of Radioanalytical and Nuclear Chemistry》2020,324(1):367-373
Journal of Radioanalytical and Nuclear Chemistry - The nanoscale zero-valent nickel (nano-Ni0) was prepared by liquid-phase reduction method and characterized by BET, XPS, FT-IR and XRD and be used... 相似文献
56.
对硫化镉反蛋白石结构光子晶体薄膜进行了可控合成,用巯基乙酸修饰的纳米晶和P(St-MMA-SPMAP)高分子小球共组装,成功地构筑了反蛋白石结构并用于可见光光解水产氢。结果表明,在可见光(λ≥420 nm)照射下,Cd S-310反蛋白石结构薄膜的光解水产氢性能比硫化镉纳米颗粒提高了一倍。这主要是因为等级孔结构反蛋白石光子晶体特性对催化剂的光催化性能的提升:首先,反蛋白石的周期性结构增加了光子在材料中的传播,提高了催化剂对太阳光的利用率;同时,大孔孔壁是由纳米颗粒堆积而成的,在反应中提供了更多的反应活性位点;此外,孔结构有利于物质的传输和分子的吸附。 相似文献
57.
Qi-Jun Li Ya-Jie Ren Qin Xie Min Wu Hua-Xing Feng Li-Mei Zheng Hua-Xin Zhang Jin-Qiao Long Tian-Shun Wang 《应用有机金属化学》2020,34(10):e5813
Two nickel complexes, [Ni(tpen)](ClO4)2.0.5CH3COCH3 ( 1 ) and [Ni(tpbn)](ClO4)2 ( 2 ), of tetrapyridyl ligands N,N,N′,N′-tetrakis(2-pyridyl-methyl)-1,2-ethanediamine (tpen) and N,N,N′,N′-tetrakis(2-pyridyl-methyl)-1,4-butanediamine (tpbn) were prepared and their catalysis for water oxidation reaction (WOR) studied. In 0.1 M phosphate buffer solution (PBS) of pH 8.0, complex 1 is a homogeneous molecular catalyst with an overpotential of ~440 mV and a Faradaic efficiency of 89%. At pH ≥ 9.0, complex 1 degraded gradually during the catalytic process and formed NiOx composite (nickel oxide with general formula NixOyHz) active for WOR. In contrast, complex 2 deteriorated under measured conditions (pH 8.0–12.0) and formed NiOx composite active for WOR. The NiOx composite derived from 1 in 0.1 M PBS at pH 11.0 showed an activity with an overpotential of ~500 mV, a Tafel slope of ~90 mV/decade and a Faradaic efficiency of 97%. Mechanisms were proposed for water oxidation catalyzed by 1 and 2 . This work revealed that the catalytic activity of the nickel complexes was related to the flexibility of the tetrapyridyl ligands and the adaptability of the coordination sphere of the nickel(II) center. 相似文献
58.
Can Li Dr. Zheng Yang Lei Wang Prof. Dr. Yinlong Guo Prof. Dr. Zheng Huang Prof. Dr. Shengming Ma 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(15):6337-6342
An efficient pincer-ligand-based cobalt-complex-catalyzed allene hydroboration affording Z-allylic boronates is described. The reaction demonstrates an excellent regio- as well as Z-stereoselectivity and a wide substrate scope that tolerates many functional groups. Based on solvent-assisted electrospray ionization mass spectrometry (SAESI-MS) studies, a rationale for the cobalt-catalyzed hydroboration involving the highly selective insertion of an allene into the Co−H bond to form Z-allylic cobalt intermediates is proposed. 相似文献
59.
Li Bin Zhang Ying Ge Junyue Liu Kehui Li Ping 《Analytical and bioanalytical chemistry》2018,410(28):7449-7456
Analytical and Bioanalytical Chemistry - Appropriate sample preparation is pivotally important to obtain high-quality mass spectrometry imaging (MSI) data. Unlike mammalian tissues, preparation of... 相似文献
60.
In this paper, by linking Fokker–Planck equations with stochastic coupled systems, a new method is provided to investigate the existence of a stationary distribution of stochastic coupled systems. Based on the graph theory and the Lyapunov method, an appropriate Lyapunov function associated with stationary Fokker–Planck equations is constructed. Moreover, a Lyapunov-type theorem and a coefficients-type criterion are obtained to guarantee the existence of a stationary distribution. Furthermore, theoretical results are applied to explore the existence of a stationary distribution of stochastic predator–prey models with dispersal and a sufficient criterion is presented correspondingly. Finally, a numerical example is given to illustrate the effectiveness of our results. 相似文献